Vehicle dies while driving

This could be catalytic converter plugging off or fuel pump or filter issue. Especially if it runs good at low speed.

Possibly, but it sounds more likely a catalytic converter may need replacing or fuel filter maybe clogged

Was the CEL on at all any time recently? Did it just completely shut off, or did the motor stumble and then die?

takes a long time to run the rediness test since there are 6 different tests to complete...

PROCEDURE 1
EVAPORATIVE EMISSION SYSTEM LEAK MONITOR
Inspection Conditions
Engine coolant temperature: 30°C (75°F) or less (The engine is stopped before the test drive is started).
Atmospheric temperature: 5 - 30°C (41 - 113°F).
Condition of A/T: Selector lever D range.
Fuel remained in fuel tank: 30 - 50% is recommended.
Time required: 16 minutes or less after started the engine.
Drive cycle pattern: One trip monitor (from start to ignition switch to "LOCK" (OFF) position. Well be completed while traveling with the following drive cycle pattern.
Test Procedure
Engine: start.
Accelerate until the vehicle speed is 89 km/h (55 mph) or more.
While keeping the accelerator pedal opening degree constant, keep the vehicle speed at 89 km/h (55 mph) or more and travel for 16 minutes.
Return the vehicle to the shop, then turn the ignition switch to "LOCK" (OFF) position.

PROCEDURE 2
FUEL TRIM MONITOR
Drive Cycle Pattern
Inspection Conditions
Engine coolant temperature: 100°C (212°F) or less.
Atmospheric temperature: -10 - 60°C (14 - 140°F).
Condition of A/T: Selector lever D range.
Time required: 30 minutes or more.
Drive cycle pattern: One trip monitor (from start to ignition switch to "LOCK" (OFF) position). Will be completed while traveling with the following drive cycle pattern.
Test Procedure
Engine: start.
Accelerate until the vehicle speed is 89 km/h (55 mph) or more.
While keeping the accelerator pedal opening degree constant, keep the vehicle speed at 89 km/h (55 mph) or more and travel for 30 minutes.
Return the vehicle to the shop, then turn the ignition switch to "LOCK" (OFF) position

PROCEDURE 3
CATALYTIC CONVERTER MONITOR
Drive Cycle Pattern
Inspection Conditions
Atmospheric temperature: -10°C (14°F) or more.
Condition of A/T: Selector lever D range.
Engine coolant temperature: Not set.
Time required: 16 minutes or more.
Drive cycle pattern: One trip monitor (from start to ignition switch to "LOCK" (OFF) position). Will be completed while traveling with the following drive cycle pattern.
Test Procedure
Engine: start.
Accelerate until the vehicle speed is 89 km/h (55 mph) or more.
Travel for 300 seconds or more while keeping the vehicle speed at 89 km/h (55 mph) or more.
Decelerate until the vehicle speed is within 80 km/h (50 mph) or less.
While traveling at 56 - 80 km/h (35 - 50 mph) for 10 minutes or more, fully close the throttle at least once in 2 minutes and decelerate for 10 seconds or more.
Do not repeat deceleration too often.
Vehicle speed may go below 56 km/h (35 mph) after the deceleration.
Stopping and braking are permitted. (If stopped or drive at 56 km/h (35 mph) or less for more than 5 minutes the monitoring may be stopped. In this case please restart monitoring from the beginning.)
After completing the above deceleration, bring the vehicle speed back to 56 - 80 km/h (35 - 50 mph) and keep it in the range until starting the deceleration again.
Repeat the above deceleration at least 5 times.
Return the vehicle to the shop, then turn the ignition switch to "LOCK" (OFF) position

PROCEDURE 4
HEATED OXYGEN SENSOR MONITOR
Drive Cycle Pattern
Inspection Conditions
Engine coolant temperature: 100°C (212°F) or more.
Atmospheric temperature: -10°C - 60°C (14 - 140°F) or more.
Condition of A/T: Selector lever D range.
Time required: 16 minutes or more.
Drive cycle pattern: One trip monitor (from start to ignition switch to "LOCK" (OFF) position). Will be completed while traveling with the following drive cycle pattern.
Test Procedure
Engine: start.
Accelerate until the vehicle speed is 56 - 80 km/h (35 - 50 mph).
While keeping the accelerator pedal opening degree constant, keep the vehicle speed at 56 - 80 km/h (35 - 50 mph) and travel for 16 minutes or more.
Stopping and braking during this operation are permitted. Keep the accelerator opening degree constant for 1 minute or more after each acceleration.
Return the vehicle to the shop, then turn the ignition switch to "LOCK" (OFF) position

PROCEDURE 5
EXHAUST GAS RECIRCULATION (EGR) SYSTEM MONITOR
Drive Cycle Pattern
Inspection Conditions
Engine coolant temperature: 100°C (212°F) or less.
Atmospheric temperature: 5 - 60°C (41 - 140°F).
A/C switch: OFF.
Condition of A/T: Selector lever D range.
Time required: 16 minutes or more.
Drive cycle pattern: One trip monitor (from start to ignition switch to "LOCK" (OFF) position). Will be completed while traveling with the following drive cycle pattern.
Test Procedure
Engine: start.
Accelerate until the vehicle speed is 56 - 80 km/h (35 - 50 mph).
While traveling 16 minutes or more at 56 - 80 km/h (35 - 50 mph) with engine speed 2,000 r/min or above, fully close the throttle at decelerate for 5 seconds or more until the engine speed reaches 1,000 r/min or under.
Do not repeat deceleration too often.
Stopping and braking are permitted (Rapid deceleration and sharp steering are not permitted).
After completing the deceleration, bring the vehicle speed back to 56 - 80 km/h (35 - 50 mph) and keep it in the range until starting the deceleration again.
Repeat the above deceleration at least 8 times by fully closing the throttle valve.
Return the vehicle to the shop, then turn the ignition switch to "LOCK" (OFF) position

PROCEDURE 6
OTHER MONITOR (Main Components, Sensors & Switches, Wire Breakage & Short Circuit)
Drive Cycle Pattern
Inspection Conditions
Engine coolant temperature:
100°C (212°F) or less (Except engine coolant temperature sensor monitoring).
30°C (86°F) or less (Engine coolant temperature sensor monitoring).
Atmospheric temperature:
5°C (41°F) or more (Except engine coolant temperature sensor monitoring).
-10°C (14°F) or less (Engine coolant temperature sensor monitoring).
Condition of A/T: Selector lever D range.
Time required: 21 minutes or more.
Drive cycle pattern: One trip monitor (from start to ignition switch to "LOCK" (OFF) position). Will be completed while traveling with the following drive cycle pattern.
Test Procedure
Engine: start
Accelerate until the vehicle speed is 56 km/h (35 mph) or more.
While keeping the accelerator pedal opening degree constant, keep the vehicle speed at 56 km/h (35 mph) or more and travel for 16 minutes or more.
Return the vehicle to the shop.
After stopping the vehicle, continue idling for 5 minutes, and then turn the ignition switch to the "LOCK" (OFF) position. Moreover, the vehicle should be set to the following conditions for idling.
A/C switch: OFF
Lights and all accessories: OFF
Transmission: Neutral

with a problem like this you must surly have a check engine light on ?
To answer your question yes an EGR valve could cause this problem on a hemi ! But would act up more cold .
And No the key thing wont work on this year of vehicle , you need to have a scanner for OBD 3 to retrieve the codes .
This sounds like a fuel problem to me have you checked fuel pressure ? and for a tuneup , remember the hemi takes 16 spark plugs it could have some of them miss firing .

bad alternator is what i have heard not 100 percent on that but a possibility.

I dont know what year it is, but if it has a MAF (mass air flow) it sure sounds like a bad one. Lee

Interstate Batteries call for battery part # MT-75
And MT-75-Mega, Both have a average price of $100 - $120 .
Your local sears sells Die Hard and they install it as well.
If you get a cheap battery, buy real nice shoes. You will need them.

I had this happen to me before. My battery had went out and I had put another in (didn't buy a new one-- it was holiday). It did this exact thing to me. The scary part is once, it was on the interstate going about 75 mph... didn't die but all gauges went to nothing. It turned out that the battery I was using didn't have enough cold cranking amps and was pulling down the alternator too much so the computer shut it down. The one time it didn't... it was because the RPH's were too high. Try checking the battery and alternator... make sure you have the right battery and have an alternator shop test your alternator if the battery is good.

My suggestion would be to replace the fuel filter, iver had this problem in my vehicles and replacing the fuel filter always seems to fix it