Jailbreaking is entirely different from unlocking . Jailbreaking is the process of removing limitations/restrictions so that 3rd party applications can be installed. Unlocking a phone is a procedure to remove any SIM/Network restrictions set on the phone by either the manufacturer of the phone or by the mobile phone's service provider.
To unlock your iPhone 3GS you can get Remote Unlock Service from
Mobile-Unlocker.com . There you have to give your Country and current Network name along with your IMEI number to get Remote Unlock Service.
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