Win shortcuts

Windows key + E = Explorer
ALT + Tab = Switch between windows
ALT, Space, X = Maximize window
CTRL + Shift + Esc = Task Manager
Windows key + Break = System properties
Windows key + F = Search
Windows key + D = Hide/Display all windows
CTRL + C = copy
CTRL + X = cut
CTRL + V = paste
Also don't forget about the "Right-click" key next to the right Windows key on your keyboard. Using the arrows and that key can get just about anything done once you've opened up any program.