I assume that you have downloaded Yahoo messenger and you have login account.
In order to chat to an individual you need to know the persons yahoo id. If you know it then go to CONTACTS/ADD A CONTACT.
By doing so, an invitation will be sent to the person and once the person is online and agrees to let you add him, then you can chat with him.
On the other hand, you can chat in 'Room'. This can be done by clicking MESSENGER/YAHOO! CHAT/JOIN A ROOM. You just need to select a desired room.
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