Have you removed the bins and cleaned under them. Sometimes the overflows and drips accumulate there.
It the refrigerator is clean, then baking soda usually helps with absorbing the odor.
But if you still have odor being produced and the unit is clean, you need to look further. If it is a chemical smell you might want to roll the unit out and check to make sure that there isn't a creamy looking liquid on the floor, which COULD be freon.
But the most likely item is that you have some bacteria growing in the drain line that is producing the odor. Suggest you mix a 50/50 mix of bleach and water and pour that down the drain to kill the bacteria. Do that several times over a day or two and see if the odor goes away.
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