There are two types of valve stems, schrader ( like the valve stems on your car ) and presta. See images on this page http://www.sheldonbrown.com/brandt/presta-schrader.html Since you are asking I assume you have presta valves. You can get an adapter to convert the presta valves for use with a schrader pump. Unscrew the small knurled nut on top of the presta valve to open it, press down and release the small top to ensure the valve is free to move. Snug up the top when it is full.
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