You want to use the custom setting on the camera. You can see what the icon looks like and the specifics on page 91 of the PowerShot S5 IS Camera User Guide Advanced version here.
http://www.usa.canon.com/consumer/controller?act=ModelInfoAct&tabact=SupportDetailTabAct&fcategoryid=223&modelid=15207#DownloadDetailAct
The custom setting will allow you to balance/adjust the brightness, contrast and saturation before you take a picture.
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