There should be a drain valve/plug under the inlet/outlet header. Opening that should allow it to drain thoroughly. Depending on where you live, this should be done in conjunction with the rest of your pool winterization. All suction and return lines should be blown out and plugged as well as all equipment including pump and filter.
SOURCE: Drain gas heater for winter
On the side of the heater, you will see the water connections. Directly underneath them, on that black component that they attach to, there is a drain plug of some description. It may be a draincock, or just a plug. In either case, simply open or remove it to safely drain your heater. In a pinch, you could also disconnect the water connections at those unions (the big grey connectors), but they can be fussy to reassemble, and you run the risk of losing the o-rings.
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