If you mean block a phone number on your iPhone, go to Settings>Phone>Blocked and you can add a number to the block list, and then you won't receive phone calls and text messages from that number. If you need more details, visit: How to Block Numbers on iPhone and Find Blocked Numbers on iPhone
Sorry but you cannot block a number yourself, your carrier has to do it for you.... Iphones do not have the feature to block numbers.
Hope this helps.....
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