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I just bought a D100 (as a backup to a D200 - nothing like being up to date with current technology! B^)). As I understand it, there is no integral flash sync connector on them. You need to get an AS-15 accessory shoe adaptor which goes on the hot shoe, and has a pc sync connector (like the D200 has on the side of the main body). Then you use a standard Metz sync cable to attach to that. The Metz 60 CT flashes have a low voltage trigger circuit and so should be safe with any camera.
Although you can still get lead acid batteries from Sonnenschein (the original oem manufacturer) for the Metz CT60 units, a better choice are the Lithium ferrite phosphate or Lithium ion batteries, now available on ebay. For example sales8phd on ebay sells a drop in replacement 6 or 7Ah battery with a charger for ~$75. In general these batteries produce more flashes per charge than the lead acid oem batteries,particularly when shooting a lot of flashes in rapid sucession.
It is likely the capacitor in the battery pack. If they are not powered up every month, they dry out resulting in long power up and recycle times. You'll need to get it replaced to rejuvenate your 60 CT-4 to its original spec.
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