How do I program this remote - Televison & Video

Without the make and model we can only guess at the appropriate method for you but you could try the following:
Setting Up the Samsung remote:

1. Turn off your device.
2. Press the appropiate device button on the Samsung remote (eg, VCR, CBL, DVD, STB etc).
3. Press the SET button on the Samsung remote.
4. Find the appropiate setup code in the manual for your brand of VCR, CBL, etc. (also available in the link provided below)
5. Using the number buttons, enter three digit setup code. Make sure you enter three digits of the code, even if the first digit is a '0'. (If more than one code is listed, try the first one.)
6. Press the POWER button on the remote control. Your device should turn on if your remote is
set up correctly. If your device does not turn on after set-up, repeat steps 2, 3 and 4, but try one of the other codes listed for your brand of device. If no other codes are listed, try each code. For VCR's try 000 through 080. For CBL boxes, try 000 thru 046. For DVD players, try 000 through 141. For STBs, try 000 through 074.

Note: the volume buttons will ALWAYS work the TV.

Source including codes: http://www.remotecentral.com/cgi-bin/forums/viewpost.cgi?175004