Nicole, I google it and the 06 Cadillac STS does appear to have a ignition relay. It will most likely be found in the engine compartment fuse/relay box. Check the attached links,instruction and guides, Good luck
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http://www.rockauto.com/en/catalog/cadillac,2006,sts,4.6l+v8,1432044,electrical-switch+&+relay,ignition+relay,3480
2006 Cadillac STS ignition relay Google Search
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