If the a/c has been turned off before the car is turned off, the smell is there when you turn it on, even if the a/c isn't turned on. It will also happen in the winter when the defroster is turned on.
SOURCE: radio, lighter, and air conditioner on 92 buick le
Check for a fuse that indicates radio and replace it if it's burnt through or melted or discolored. The Buicks have dash controls that require expensive repairs sometimes to get the temperature controls to work so some people jump around the controls by installing a separate toggle switch that directly turns the AC unit off and on for 92 through 94 Buicks. Any AC shop can install the bypass wires.
The burning smell could be due to gas leakage in the engine compartment. The gas smell is being sucked into the fresh air intake of the air conditioner. It can be avoided by checking either fuel pressure regulator or fuel injector.
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