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If possible, use a second CD player/burner to burn a CD. If can't borrow one, either internal or external (USB), they are fairly cheap second hand. I suspect your CD player has become defective, maybe only in burn mode. Can you burn anything (eg, software) using this item ? ie is it only iTunes that's affected ?
You can get the battery from eBay only. Check out: http://cgi.ebay.co.uk/Battery-For-Asus-M51-M51S-X53SA-X53-Pro31-90-NIA1B1000_W0QQitemZ130323424733QQcmdZViewItemQQimsxq20090808?IMSfp=TL090808134002r14373
If you are burning using software you have to tell it which device to use as a burner first. Usually there is a drop down menu of some sort for it, explore your burning software a little more. Most Drives can burn Cds these days, I'm sure it can.
Read on your optical drive. If it burns CD's it reads CD-RW. In order to burn DVD's it needs ro read DVD-RW. If it reads DVD-ROM it will only read DVD's not burn them.
A good external burner is Plextor. You can get one at Walmart, or you can check Ebay and find an internal to replace the one in your machine. They are fairly easy to replace, and you won't have a bulky external to carry around.