Here's the Microsoft way - note that all Win7 keyboard shortcuts begin with CTRL-ALT-(your shortcut key here).
Note also that a desktop shortcut must already exist to which to be invoked by the keyboard shortcut.....
http://windows.microsoft.com/en-us/windows-vista/Create-keyboard-shortcuts-to-open-programs
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The way the Internet community does it:
www.autohotkey.com - freeware - allows you to "package" a number of
keystrokes into a "keyboard macro" and invoke that macro thru
the use of a "hotkey." Keyboard macros can be as short as one
function key, but some Win7 function keys cannot be ove-written, such as F5
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Thanks for your comment! I had come across SharpKeys 3.0 in the meantime and was able to revive those 'dead' function keys (for this HP keyboard used on a non-HP computer) quite nicely... e.g. F9 was mapped to 00_43 (did nothing on a Sony Vaio) and I mapped it to open Outlook (E0_6C), and mapped F12 to E0_21 (the calculator) etc. Can also recommend this (free) tool.
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