The manual is available as a PDF here:
http://www.lg.com/us/tv-audio-video/televisions/LG-lcd-tv-32LE5300.jsp . Click on Support and then the Televisions Manual on the right. Just above is a link to Adobe Reader if you need the program.
LG doesn't always support Mac systems but that shouldn't change the manual access if you have a working optical drive. If you have Adobe Reader, then the problem might be that the disc won't autoplay. Try manually accessing the contents of the optical drive. (Open the File explorer and then the optical drive.)
Next: is your DVD player a stand-alone device or is it part of the computer? How have you connected the TV and the DVD player? The model number would help. Generally, you need to change the source for the TV to match where the DVD player's cables are going into the TV. There is a button for this on the TV's remote (and on the TV, just left of the power button) - labeled Input. The DVD player should be off when the TV is turned on and then set to this source. (The TV can get confused otherwise.)
The HDMI and HDMI2 ports should work with a PC connection (1920x1080 with the input label set to PC for the TV if you change the label for the HDMI ports). The entire list of inputs should be TV, HDMI1, HDMI2, HDMI3, PC (VGA), AV in 1, Component in 1, AV in 2, Component in 2, HDMI4.
I hope this helps.
Cindy Wells
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