The battrey is probably to old and will not charge. try another controller and see if that charges and stays charged when you unplug it. or try pressing the reset button on the controller.
Turn off your PS3 console and disconnect it from the power supply. Insert the USB cable provided with your console into an open contoller port. The controller ports are found on the left side of the front of the PS3. Insert the other end of the USB cable into the back of the wireless remote controller that you want to sync with the PS3. Reconnect the power supply to the PS3 and turn it on. The wireless remote control should sync automatically with your console. If it does not begin automatically, press the "PS" button at the center of your controller. This will begin the process. Once the sync is complete, you can disconnect the USB cable and the controller will communicate with your PS3.
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