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The first thing you need to substantiate is the fact that there is enough water in the system. It will be a closed loop system requiring approximately 10 psi/ floor. (Only a rule of thumb). Usually when one protion of the system works and the other does not, it is an issue of water quantity available to circulate through the combination of loops. If you have to add water, you will probably have to purge air from the highest points in the system. Even if there is an "Airtrol" fitted in the bottom of the expansion tank, bleeding the high points will eliminate air quicker.
The hot water portion of the loop should only be going through a heat exchanger that transfers the loop temp to the domestic water circuit and the three way valve is probably a 'mixing valve' utilized to maintain a certain loop temperature on the primary loop.
Go to honeywell.com
Under red welcome sign
Bottom red highlighted box literature/image search
Type in thermostat model number
Click on arrow to right
Then click on the PDF files owners manual / installation instructions
If you can’t find what you want, the bottom left and bottom of web
Page, they have homeowners assistance and Home products to get the help you need.
R comonY cool W heat G fan C other side of 24 unless you are battery operated. On the back of the Tstat tou should have switch that says gas or electric this controls how the fan operates. If not go into programing and program 1 stage heat one stage cool.Let me know I will walk you thru this.