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Which battery holder are you using? The small one or the grip MB-15? If it is the MB-15 make sure it is screwed in tight. If it is the small one then make sure your batteries are in the correct direction. If that does not work call Nikon Film 1-800-645-6687.
We will assume you know how to load the film to the red mark. If the film is not advancing a couple of things could be happening. When you close the back door it is not engaging the film to hold it against the take-up spool. If so then that needs to be fixed. The other thing to check is the left side where the film cartridge goes in, does it turn. If not it is binding the film cartridge. Nikon Film 1-800-645-6687
I do know that on earlier models like the N90s and 8008s, the small nut that holds the battery clip in place activated a cut off switch. If the switch was faulty, the camera would not turn on. There may be a similar switch in the F100.
This is an easy one. With the battery grip attached, you can only have either Shutter Priority or Aperture Priority work properly. You can change it with the custom function settings of the camera. So you can change it to work with Aperture Priority if you use that more so then shutter priority won't work.