Your primary Facebook email address is the address you use when you log in to your Facebook account.
Additional email addresses can be listed on your profile as well if you chose.
Changing, adding or deleting email addresses on your Facebook account is easy to do.
Log in to your Facebook account.
Select the Account menu in the upper right corner of the screen and select Account Settings from the drop-down menu.
Click on General from the list in the left panel of the Account Settings page.
Click on Email in the main window to expand the section.
Click Remove"next to any email address to delete it.
Click Add another email and type a new address into the space provided.
Click the radio button next to any email address to designate it as the primary Facebook email address.
Click Save Changes.
Facebook sends a confirming email.
The change does not take place until you open the email and confirm the change.
http://www.facebook.com/help/?faq=162801153783275&ref_query=email+ad
How do I add or remove an email address from my account
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