Well, the short answer to your question is "No, it won't work". The Dell Dimension 4600 does not have any PCI Express slots in it, therefore you can't install it, and therefore it won't work. But, if you installed a PCI sound card, it would work. The BIOS would recognize the add-on sound card, disable the onboard sound, and your sound will start going through the expansion card instead. Hope this helps.
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