There is more than an issue to cause this. 1st that some iphones are locked on a specific operators, with a contract for one or couple of years. after end of contract you can unlock the iphone at the operator and can use any sim card. 2nd the sim card it self may be damaged & cannot be read by iphone, please try it in another phone and see if it is working.
To know if your iphone is officially locked/unlocked by the model number, you can google it.
You need to unlock and then apply for a new sim card from your desired network provider. I suggest you can approach Unlocking4u.com and specify the country,locked network of iPhone 4S. Based on the availability you can get the permanent unlock service along with free instructions.
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