The squealing sound generally comes from a circulator pump, if it has a drive coupling between motor and impeller housing there is an oil cup/or oil hole, add oil until it is full! If it is a cartridge style circulator you may have to replace it.
Sometimes air in a system will cause this squeal noise as well. Purging the air out of system may be required. If you need to know how to purge a system there is a good pdf file at this link for $8.95 The Basics of Purging Air
From your Forced Hot Water System
Troubleshooting A Leaking Boiler
Miller Furnace Books Repair
The Expansion tank is factory set to 12 psi and the only way to tell if it remains with 12 psi is to drop the system pressure to zero and check the tank with a pressure gauge. If water comes out the air valvestem when you apply the pressure gauge, the tank is bad, replace it! If there is less then 12 psi on the tank add air to 12 psi and open water valves back up to normal operating pressure. Usually the feed valve will automatically stop at the preset setting.If the boiler is leaking water out any relieve valve drains, the feed valve, relief valve and or expansion tank may need to be replaced.