From the Manual:
1. With your Playstation 3 game Console on and the ON/OFF switch on the bottom of the controller set to on. Plug in the USB receiver into a USB port in the Playstation 3. The LED will flash slowly.
2. Press the "connect" button on the receiver. The LED will flash rapidly.
3. Press the "menu" button on the controller. The four channel lights will flash rapidly until the sync process is done. When the sync process is done one of the channel lights will remain solidly lit.
The manual can be found here in PDF format.
http://assets.dreamgear.net/manuals/DGPS3-1324.pdf
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