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I honestly don't ever recommend buying gold, for more reasons than the fact that it kills the spirit of the game. For one, a guildie of mine got hacked trying to buy gold because he gave them his account's email when they asked for one.
He said they also asked for his real name (which, durr, will be on your account information, too). They'll sell you gold all right, but then they'll turn around and steal the account back from you, because all they really need is the email if you don't have an authenticator, take the gold you bought from them and resell it.
I don't recommend it. It's not hard to just earn gold. Level some gathering professions like Mining or Herbalism, gather, and sell the mats. You'd be surprised what people will pay to be lazy. I recommend an authenticator too to prevent future hacking.
These sights are used by gold farmers to sell gold that they have spent lots of time collecting to other players. It is against the terms of service established by blizzard to sell or buy gold, if you are going to purchase gold make sure you do so carefully as it can result in a permanent ban from the game.
There is some confusion here concerning the two uses of karat. For diamonds and precious stones the karat is a measure of mass (weight) equal to 200 milligrams (or 0.2 grams). In the context of gold alloys, the karat is a measure of purity. Pure gold is 24 kt, 18 karat is 0.75 pure or 75 % pure gold and 25 % other metals (copper or something else), The most prevalent type of gold in North America is 14 kt gold, which is 58.333 % pure gold and the remainder (41.66%) other metals. To get to back to your question, you cannot relate the purity of gold piece to its mass (weight) because all it says is that the piece of gold is close to 100% pure.