SOURCE: PS3 controller Problem
I just fixed mine. The controller itself needs to be reset. There is a reset button on the back of the controller, above the top right hand corner of the square with all on the information and barcode. Press it with a sharp tipped object while still connected to the PS3 via USB cable. Then press the PS button and you should be back on wirelessly.
SOURCE: My controller will not connect on my ps3.
Sounds like the controller knows it belongs to the other PS3. It has already "paired" with one console, so that's why you're having a hard time trying to get it to pair with console #2, comprende?
Make sure console #1 is a "hard off", like switched in the back. Now flip your controller over & put a pencil or pen tip in the reset hole. ( Just to the right of the center screw hole.) NOW connect said controller with the USB to console #2. Hold the PS button for two seconds. All 4 lights will flash 5 times, then the 1 light should stay on, Boo-ya! You're PAIRED!
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