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Are you sure you have the correct model number? Because that model number should only have 2 Ram Slots located right below the processor slot. I put a picture of the ASUS P4S533-VM motherboard at the bottom of this answer for you to check.
If that is the correct motherboard model number then it takes up to 2GB of PC2700 DDR333 Ram (2 sticks of 1GB PC2700 DDR333 Ram)
Unfortunately it won't let me link the page directly, but if were to go to this particular Asus page and:
1. Select motherboard for product 2. SocketA(462) for the "Series" box (may have to scroll down) 3. And A7N266-VM for "Select Model" box then search you will get a whole list of downloadable stuff, including a number of user manuals.
If you're prompted for an OS to choose just pick XP though it doesn't matter I don't think if all you want are the manuals.