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1st option:Here's what you'll need to do. On the XMB on the PS3, go to Settings, then go to Accessory Settings, then Register Bluetooth Device. Select Register Headset/Microphone/Headphones. Press X to accept the 'Start Scanning' mode for the PS3. Then.... With the Motorola pairing can be clumsy. It involves pressing and holding the call button while the microphone is folded closed, then quickly opening it up once the blue LED comes on. 2nd option:Hold down the answer call button on the bluetooth headset until the light is solid (not flashing). When the PS3 detects your headset, it'll ask for a pass. The pass should be "0000" (four zeros).
Go to your bluetooth settings and make your phone discoverable, normally you need to hold the power button down on your headset until it flashes red and blue, then you will need to select the headset on your phone, the default code is usually 0000