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if other IM like yahoo have the possibility to ofer someone an invite to view webcam ...this isnt possible in msn ..the only way you can do thet is when you click video call ...and this is available when both are using the msn program installed into the pc...and a new version ...if one is using a web related chat this became impossibe ...so ...take a good look and see if you have the button for audio video call..should be 4th from the left of the messeging window...it looks like a calling device ..with a film band on ...you may need to upgrade to a new version if you do not have such a button ...as long as in is working on other IM mean that the problems is on msn instalation
Try the following:
1. Install the latest drivers, which will have support for Vista. Your drivers are probably ment for XP and below.
2. You could also try with an installation guide for sound and video. Most IM has this function, i.e. MSN Messenger.