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It may be important to have an idea as to what caused the stain/discoloration. Carbona (http://www.carbona.com/home.php) has different products specific to the various reasons for the problem. You may be able to use bleach, depending on the fabric affected. Some white material turn yellow with bleach
Hope this helps ~ Good luck!
If it's gunk or build up the marks should wash away. In this case run a long cycle using "affresh" or "washer fresh" with an empty load and use the hottest water available to help rinse the gunk out.
If the marks do not wash away, it could be grease due to a bearing failure. Listen for loud growling or grinding either by spinning the drum by hand or putting it into a spin cycle. If this is the case, the rear tub assembly (contains bearing) will need to be replaced. Not much can be done about the ruined clothes :(
What you could possibly try, is run an empty load, to wash the washer drum clean of sediment. If the washing macine drum is stained, clean it by hand with a cleaning compund, like clorox or some other kind of cleaning solution. Another thing that you can try, is to use the dish washer cleaning solution that they sell, to clean dish washers of sediment. It comes in a small white, plastic square container and Walmart sells it.