Ammonia is toxic to breathe, even at low levels. Ammonia fumes are very irritating and corrosive to the eyes, nose and airways. Fumes may cause a burning sensation, coughing, wheezing, shortness of breath, laryngitis, rhinitis and watery eyes, even at low levels. People with asthma or other respiratory problems may be especially sensitive to ammonia fumes, as may individuals with corneal disease, glaucoma, or severe liver damage.
I had a problem very similar, I emailed Dometic, they said an animal had probably sprayed the coils with urine and that I should wash the coils with plain water. However this is very remote because the AC coils are inside on the ceiling and no access to vent outside. I think the cause was ambient urine collected on the coils from the air in the cabin from the on board toilet. I washed the coils (inside ones) 5 times with vinegar, mild bleach solution and mild Dawn solution then rinsed throughly, the smell went away mostly and is getting better.
SOURCE: Ammonia smell when Dometic Air Comditioner is on
sounds like you have an old unit and it has a leak , the real old units where filled with ammonia as the gas
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make sure your dump tank(s) valves are closed, otherwise air can be sucked into the ac and appear to be coming from the ac unit.
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