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Depends on the heater/fixture. All devices of this sort list minimum clearances between sides and combustable materials.

As to will insulation be a problem, depends what you call a problem. Will it need to be removed? Most likely yes if for no other reason then to provide cavity/freespace to install the heater. For a exterior wall application a small baseboard electric heater would be a better solution to the problem or a toekick electric heater under a sink vanity.

Hi - I have some suggestions. The following factors effect picture quality:
1. Source (because LCD TVs have much higher picture quality than traditional CRT "Tube" TVs, the worse your source material, the worse it looks on a LCD TV).
DVD and Sky/Digital TV should look excellent on this TV when connected with a good quality Scart lead (nothing too expensive, but a Oxygen Free Copper Gold lead may help) directly into one of the TV's Scart inputs (avoid using "switching" boxes for multiple equipment).
Also, bear in mind that this is a HUGE screen (40 inches I think) and will REALLY show up bad source material.
The best advice I can give is, if you have HD-ready equipment use HDMI connections for everything (ideally with an HD-uplscaling DVD player which will "improve" the quality of standard DVDs on the TV - I recommend models by Philips) and check that you are in "Movie" or "Cinema" mode on the TV.
Make sure that all of your equipment, like your Sky digibox, is set to 16:9 mode (not 4:3) aswell to preserve the true widescreen aspect ratio.
Hope that helps!