There are a couple of things that could cause this.
First, a worn belt can result n slippage and squealing when the compressor load is applied.
Second, a worn out compressor clutch can result in a metal-to-metal contact when the clutch engages. This will cause slipping and squealing.
Third, the compressor shaft could be locked up, so that when the clutch engages, the belt slips over the pulley and squeals.
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