Place a spark plug tester in your number #1 ignition lead and confirm spark.- No spark = possible ignition module failure if spark from coil is present.
Test the fuel line pressure for 12 PSI.for throttle body fuel injection systems on 1987 to 1995 - If reading is low replace fuel pump. If reading is zero lbs check relay.
Compression test for acceptable compression.
If you have spark, fuel and compression, static time the engine and try again to start the vehicle.
PS: If your vehicle is a standard shift you have a clutch safety switch and a column mounted ignition switch that should also be considered.
Here is some more info that may help:
How to Test the Fuel Pump on GM TBI Fuel Systems How To Check Engine Compression GM 3 5L 4 2L
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