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the air con does nothing more than cool the air
if the temperature is not getting hotter then there is a problem in the heater system of the car
that could amount to blocked heater core , heater control not working ( module control) low coolant level, and air lock in the system or faulty thermostat stuck open
Sounds like you may have combustion gasses creating an air lock in the cooling system. Or plugged heater core / radiator. Definitely a circulation problem of some kind either flow of hot antifreeze is restricted or the heater should blow very hot air especially when the car heats up so long as all the ducting and heater controls are functioning properly. If the vehicle has been overheated you more than likely have combustion gasses in the cooling system. Water pump will not work properly for combustion gasses that mix with coolant. Check to see if the coolant is beginning to get a little oily and dirty, this will indicate combustion gasses entering cooling system.
Sounds like either low coolant or air in the cooling system. Either you need to bleed air out of cooling system or repair possible leak in system. When there is air in cooling system and it goes into your heater core, heat is not transferred to the air blowing out of your vents.
This may be a puzzle...
The seicento (I drive the same car) likes to create problems in the heater section of the cooling system. The small pipes to it (behind the carburator) may be blocked or the entire heater may simply be dirty. Flushing the system with a water hose may help. Usually this problem starts slowly and goes away if you re-start the engine and then excellerate a few times. Check if your heater blows hot air - if yes, and if he keeps blowing hot air (does not cool down and get cold) ther is no blockage. If you have a blockage, your heater will only blow hot for a little while and then comes normal cool air - if this is the case, you have a blockage right in your heating system which runs your cooling system hot and the cap of your cooling tank will start leaking. This is a comon problem on older Seicentos....
Other general problems can also be the case, like defective thermostat, fan motor does not come on (check fuse and relais first).
In some cases, ther might be some air trapped in the cooling system and doing the above will also cure it. At last, check if your water pump is working.
Make sure that the radiator fan is going off like it is suppose too. Also, some vehicles have a shut off on the water inlet hose to by-pass the heater core for the A/C when it is running in the summer. This could be malfunctioning.
Did you run engine from cold, with heater on when you refilled the system? Try again, rad cap off, with heater on, and let engine get up to operating temperature, make sure you have good flow through rad ,leave cap off, until rad fan comes on to cool returning coolant to rad at least twice. Give engine a little extra rev, for 5 seconds or so, every once in a while to make sure flow getting through heater core, and add coolant as necessary. See if that helps, as it may just be an airlock in system. If your cooling system has any bleed screws incorporated, crack them once in a while as well.